Welcome

To Ghazwa Aldoori's website
Home     E-portfolio     Main Courses     About Me     Contact Me     Site Map      

University of Pennsylvania

Chemistry Department

MCE Program/ Cohort 8

Chem. 501

Dr. Roberts

Add your content here
 

Arrhenius Kinetics

Ethoxide + Methyl iodide

 

Objection:

An attempt to quantify the dependence of reaction rates on temperature. Investigators Hecht and Conrad in 1889 collected data of reaction rates of ethoxide and methyl iodide.

Arrhenius examined the data and found out that it could be represented adequately by an expression called Arrhenius equation:

Our purpose is to present this data in a graphical form and calculate the activation energy.

Introduction/ Analysis

The Current understanding of how a chemical reaction takes place is based on a

collision model. In this view, Kinetic energy of the atoms and molecules in a reacting

system is transformed into an increase in potential energy of reactant molecules

which makes the reaction takes place. Molecules must collide with certain

minimum amount of energy necessary to break bonds and force the molecule through

unstable intermediate states to go to product. This minimum amount of energy that

must be overcome is called the activation energy.

Another factor affects rate of reaction is the concentration of reactants. The greater

the concentration of the reactants, the greater the collisions per second. In line with

this expectation, the rate of a chemical reaction exhibits a dependence on the

Concentrations of reactants rose to a small integral power equal to the number of

moles of the reactants.

 

The rate of chemical reactions also increases with temperature. This is a phenomenon seen in warm weather; Frozen food can be preserved for a long time but will spoil at room temperature. A rule of thumb used by chemist to estimate the rate of reaction is that the rate approximately doubles for every 10 degree Celsius rise in temperature. This would suggest that the relationship between the reaction rate and temperature is exponential.